Nuclear Desalination

Harsh Parikh
March 20, 2024

Submitted as coursework for PH241, Stanford University, Winter 2024

Introduction to Nuclear Desalination

Fig. 1: Reverse osmosis desalination plant. (Source: Wikimedia Commons)

Nuclear desalination presents a promising solution to the pressing challenge of potable water scarcity, particularly in arid and semi-arid regions across the globe. This technology harnesses the thermal energy generated from nuclear reactors, traditionally considered a byproduct, to desalinate seawater, offering a sustainable alternative to conventional water supply methods.

The necessity for such technology is underscored by several compelling global trends. Firstly, the world's burgeoning population significantly heightens the demand for fresh water, straining the existing natural resources to their limits. Nuclear desalination stands as a viable option, capable of meeting this escalating demand and ensuring communities have access to essential water supplies for drinking, sanitation, and agriculture. Additionally, the phenomenon of climate change exacerbates water shortages by disrupting traditional precipitation patterns, leading to droughts and floods in various regions. This unpredictable variability renders nuclear desalination a reliable source of freshwater, capable of securing water supplies in regions prone to climate-induced scarcity.

Moreover, the lack of access to clean and safe drinking water in many parts of the world poses a severe public health challenge, facilitating the spread of waterborne diseases. Nuclear desalination can play a crucial role in addressing this issue by providing a consistent supply of clean water, thereby enhancing public health outcomes and reducing reliance on potentially contaminated local water sources. Environmental and agricultural challenges, such as increased salinity in natural water sources due to overuse and environmental degradation, also necessitate the adoption of nuclear desalination. This technology offers an alternative source of freshwater, reducing the demand on natural water bodies and supporting sustainable agricultural practices.

The global adoption of nuclear desalination is further evidenced by the operational successes in countries such as Saudi Arabia, Australia, and Israel, which have turned to this technology to meet a substantial portion of their water needs. [1] More than 300 million people worldwide now rely on desalinated water, underscoring the technology's role in combating global water scarcity. [1] The International Atomic Energy Agency (IAEA) supports this endeavor through tools like the Desalination Economic Evaluation Program (DEEP) and the Desalination Thermodynamic Optimization Programme (DE-TOP), which facilitate the assessment of nuclear desalination projects, enhancing the ability of countries to explore and implement this technology efficiently. [1]

Thermal Desalination Process

Thermal desalination processes, such as Multi-Stage Flash (MSF) and Multi-Effect Distillation (MED), play a pivotal role in leveraging waste heat from nuclear reactors to produce fresh water. Historically, MSF was a dominant technology in this field, employing a series of stages where seawater is heated and then rapidly cooled, causing it to 'flash' into steam, which is subsequently condensed into fresh water. [2] This process, while effective, is characterized by its high energy intensity, making it less sustainable compared to newer technologies. [2]

In recent times, however, the focus has shifted towards more energy-efficient methods such as Multi-Effect Distillation and Reverse Osmosis (RO). MED operates under a principle similar to MSF but is more energy-efficient. It involves multiple stages (or effects) where seawater is boiled in a sequence of vessels, each at a lower pressure than the last. [2] This sequential boiling utilizes the heat from the previous stage, significantly reducing the energy input required per unit of water produced. [2] The ability of MED to handle high levels of salinity with minimal pre- treatment further enhances its appeal, marking it as a superior choice in terms of energy efficiency and operational feasibility.

Reverse Osmosis

Reverse osmosis (RO) powered by nuclear-generated electricity represents a synergistic fusion of nuclear energy and water purification technologies, offering a sustainable solution to global water scarcity challenges. Central to this process is the nuclear power plant, utilizing nuclear fission to convert water into steam, thereby driving turbines to produce clean, efficient electricity. This electricity is crucial for operating high-pressure pumps in RO systems, which pressurize seawater against a semipermeable membrane, effectively filtering out salts and impurities to produce fresh water. [3]

The semipermeable membrane, a key component of RO technology, selectively allows water molecules to pass while blocking salts and mineral ions, facilitating desalination under high pressure. [3] (See Fig. 1) Advances in membrane technology and energy recovery systems have significantly enhanced the efficiency of modern RO plants, reducing electricity consumption. For instance, contemporary RO systems have achieved reductions in energy consumption to as low as 3 kWh per cubic meter of desalinated water, a significant improvement from older systems which could consume upwards of 5 kWh per cubic meter. [4] This efficiency is bolstered by the integration of nuclear power, providing a reliable and consistent energy source that reduces the carbon footprint of desalination operations.

The environmental advantages of nuclear-powered RO systems are notable, especially in their contribution to reducing greenhouse gas emissions compared to traditional fossil fuel-based power generation. By leveraging the low-carbon energy from nuclear reactors, RO desalination plants can operate more sustainably, aligning with environmental sustainability goals and contributing to the mitigation of global water scarcity. The intersection of nuclear energy and RO technology highlights a forward-moving direction in the integration of clean energy solutions with advanced water treatment processes, marking a significant advancement in addressing some of the most pressing environmental challenges of our era.

Current Implementation

In the realm of desalination and water resource management, Israel and Singapore stand as exemplary case studies, demonstrating the practical applications and benefits of integrating advanced desalination technologies, including those powered by nuclear energy.

Israel's approach to desalination has been transformative, positioning it as a global leader in water innovation. Facing chronic water shortages, Israel has heavily invested in desalination technologies, notably reverse osmosis (RO), to meet a significant portion of its water demand. [5] As of recent years, desalination plants along its coastline supply over 40% of the country's domestic water needs. [5] This strategic shift not only ensures a reliable water supply for its population but also supports agricultural and industrial sectors, thereby enhancing national water security and resilience against droughts.

Singapore's strategy in water sustainability focuses on diversifying its water sources, with desalination and wastewater reuse being key components. The city-state aims to increase its reliance on desalination, recognizing its potential to provide a drought-resistant water source. Singapore's desalination plants are part of its Four National Taps strategy, complementing water from local catchment areas, imported water, and NEWater, its branded reclaimed water. [6] By 2060, Singapore plans to meet up to 30% of its water demand through desalination, highlighting its commitment to sustainable water management and technological innovation in overcoming geographical and environmental limitations. [6]

Challenges and Considerations

The integration of nuclear reactors for direct thermal desalination, such as flash distillation, while effective in water production, faces economic and practical challenges primarily due to its high operational and maintenance costs. This process demands significant energy to evaporate seawater, leading to increased operational expenses and making it economically less viable compared to more energy-efficient methods.

In light of these challenges, there has been a strategic pivot towards Reverse Osmosis (RO) desalination, acclaimed for its lower energy consumption and operational costs. Despite the higher initial capital investment required for RO systems, their long-term efficiency and cost- effectiveness present a strong case for their adoption. Advances in membrane technology and energy recovery systems have played a crucial role in reducing the cost per cubic meter of produced water, making RO desalination an economically feasible solution for addressing water scarcity.

The economic landscape of RO desalination has evolved significantly, with energy expenses constituting a major portion of operational costs. However, the sensitivity of these costs to the salinity of the source water and technological advancements have led to a notable decrease in expenses. For example, Israel has successfully reduced the cost of desalinated water to 53 cents cents per cubic meter, highlighting the cost-effectiveness of RO in regions that adopt such energy-efficient practices. [7]

The reduction in energy requirements, facilitated by technological innovations like nanotube membranes and electrochemical processes, underlines the pivotal role of energy efficiency in enhancing the long-term economic viability of RO desalination. As energy costs vary, the overall impact on desalination expenses underscores the importance of continuing to advance in this field to maintain cost competitiveness and further reduce the financial burden of desalination projects.

Future of Desalination

The future of desalination technology promises significant advancements through the development of innovative processes such as Membrane Distillation (MD) and Electro-deionisation (EDI). These technologies have the potential to further enhance the efficiency of desalination processes while reducing operational costs, thereby improving the synergy between nuclear energy and desalination.

Membrane Distillation (MD) is a technology that utilizes thermal energy to vaporize water through a hydrophobic membrane, which only allows vapor to pass through while retaining the dissolved salts and impurities. [8] The vapor is then condensed on the other side as fresh water. This method can be particularly advantageous when integrated with nuclear power, as the low-grade waste heat from nuclear reactors could be utilized to drive the distillation process, thereby maximizing energy efficiency and minimizing the carbon footprint.

Electro-deionisation (EDI) is another promising technology that combines semi-permeable membrane technology with ion-exchange media to remove ionized species from water. [8] EDI is especially beneficial for producing ultra-pure water without the need for chemical regenerants, making it an environmentally friendly alternative. [8] When powered by electricity from nuclear sources, EDI could offer a sustainable solution for high-quality water production with minimal environmental impact.

Ongoing research and development in the field of desalination are aimed at enhancing these technologies to achieve higher efficiency and lower costs. Innovations in membrane materials, energy recovery systems, and process optimization are central to these efforts.

© Harsh Parikh. The author warrants that the work is the author's own and that Stanford University provided no input other than typesetting and referencing guidelines. The author grants permission to copy, distribute and display this work in unaltered form, with attribution to the author, for noncommercial purposes only. All other rights, including commercial rights, are reserved to the author.

References

[1] K. C. Kavvadias and I. Khamis, "The IAEA DEEP Desalination Economic Model: A Critical Review," Desalination 257, 150 (2010.

[2] F. E. Ahmed, R. Hashaikeh, and N. Hilal, "Hybrid Technologies: The Future of Energy Efficient Desalination - A Review," Desalination 495, 114659 (2020).

[3] J.-S. Kim and H. E. Garcia, "Nuclear-Renewable Hybrid Energy System for Reverse Osmosis Desalination Process," Trans. Am. Nucl. Soc. 112, 121 (2015).

[4] M. A. M. Khan, S. Rehman, and F.A. Al-Sulaiman, "A Hybrid Renewable Energy System as a Potential Energy Source for Water Desalination Using Reverse Osmosis: A Review," Renew. Sustain. Energy Rev. 97, 456 (2018).

[5] E. Spiritos and C. Lipchin, "Desalination in Israel," in Water Policy in Israel, ed. by N. Becker (Springer, 2013).

[6] B. Susantono and S. H. Li, "Urban Water Future: What Can We Learn from the Singapore Experience?," CSID J. Infrastruct. Dev. 4, 4 (2021).

[7] A. Tal, "Addressing Desalination's Carbon Footprint: The Israeli Experience," Water 10, 197 (2018).

[8] G. Amy et al., "Membrane-based Seawater Desalination: Present and Future Prospects," Desalination 401, 16 (2017).